Serveur d'exploration sur l'Indium

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Crystal structure of In-based cuprates: (In, Cu)S[Sr]2YCu2O6+δ (1212), (In, Cu)(Sr, Ho)2(Ho, Ce4+)2Cu2O8+δ(1222)

Identifieur interne : 000A07 ( Russie/Analysis ); précédent : 000A06; suivant : 000A08

Crystal structure of In-based cuprates: (In, Cu)S[Sr]2YCu2O6+δ (1212), (In, Cu)(Sr, Ho)2(Ho, Ce4+)2Cu2O8+δ(1222)

Auteurs : RBID : Pascal:02-0073209

Descripteurs français

English descriptors

Abstract

The indium-based cuprates with perovskite-like structure (In, Cu)Sr2YCu2O6+δ and (In,Cu)(Sr,Ho)2(Ho,Ce)2 Cu2O8+δ, belonging to the homologous series (In, Cu)(Sr,Ln)2(Ln, Sr)k-1CukO2k+2+δ with k = 1 (In,Cu-1212) and (In, Cu)(Sr, Ln)2(Ln, Ce)k+1Cu2O2k+6+δ with k = 1 (In,Cu-1222) have been obtained. Their structure has been refined at room temperature using X-ray powder diffraction data. The samples with the nominal compositions (In0.5Cu0.5)Sr2 YCu2Ox and (In2/3Cu1/3)(Ho1/3Ce2/3)3Sr2Cu2Ox appeared to contain phases with lattice parameters a = 3.8163(1), c = 11.9785(6) A (In,Cu-1212, sp. gr. P4/mmm) and a = 3.8272(0), c = 29.0774(3) Å (In,Cu-1222, sp. gr. I4/mmm), respectively. Rietveld refinements were carried out. The real composition of these phases may be written as (In0.89Cu0.11(3))Sr2YCu2O6.98(4) (In,Cu-1212) and (In0.98Cu0.02(1))(Sr1.25Ho0.75(2))(Ho1.89Ce4-0.11(5))Cu2.00O9.00 (In,Cu-1222). The refined composition of these phases after oxygen treatment was formal to be (In0.82Cu0.18(2))Sr2YCu2O7.00 (In,Cu*-1212) and (In0.87Cu0.13(1))(Sr1.52Ho0.48(2))(Ho1.95Ce4+0.05(3))Cu2O9.00 (In,Cu*-1222). The Cu formal charge (FC Cu) in the (In,Cu)-1212, calculated from electroneutrality condition of the refined phase composition, was almost the same as before (FC Cu ∼2.04) and after (FC Cu∼ 2.09) the oxygen treatment (underdoped phase). On the contrary, the FC Cu for the (In,Cu)-1222 increased after oxygen annealing (from -2.08 to -2.30) (overdoped phase). The non-optimal values of the Cu formal charge could be a possible reason for the absence of superconductivity in these samples.

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Pascal:02-0073209

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<teiHeader>
<fileDesc>
<titleStmt>
<title xml:lang="en" level="a">Crystal structure of In-based cuprates: (In, Cu)S[Sr]
<sub>2</sub>
YCu
<sub>2</sub>
O
<sub>6+δ</sub>
(1212), (In, Cu)(Sr, Ho)
<sub>2</sub>
(Ho, Ce
<sup>4+</sup>
)
<sub>2</sub>
Cu
<sub>2</sub>
O
<sub>8+δ</sub>
(1222)</title>
<author>
<name sortKey="Afanasseva, I N" uniqKey="Afanasseva I">I. N. Afanasseva</name>
<affiliation wicri:level="1">
<inist:fA14 i1="01">
<s1>Department of Solid State Physics and Chemistry, M V. Lomonosov State Academy of Fine Chemical Technology, 86 Vernadsky prosp.</s1>
<s2>117571 Moscow</s2>
<s3>RUS</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Russie</country>
<placeName>
<settlement type="city">Moscou</settlement>
<region>District fédéral central</region>
</placeName>
</affiliation>
</author>
<author>
<name sortKey="Kuz Micheva, G M" uniqKey="Kuz Micheva G">G. M. Kuz Micheva</name>
<affiliation wicri:level="1">
<inist:fA14 i1="01">
<s1>Department of Solid State Physics and Chemistry, M V. Lomonosov State Academy of Fine Chemical Technology, 86 Vernadsky prosp.</s1>
<s2>117571 Moscow</s2>
<s3>RUS</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Russie</country>
<placeName>
<settlement type="city">Moscou</settlement>
<region>District fédéral central</region>
</placeName>
</affiliation>
</author>
<author>
<name sortKey="Mitin, A V" uniqKey="Mitin A">A. V. Mitin</name>
<affiliation wicri:level="3">
<inist:fA14 i1="02">
<s1>P.L. Kapitza Institute for Physics Problems</s1>
<s2>Moscow</s2>
<s3>RUS</s3>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Russie</country>
<placeName>
<settlement type="city">Moscou</settlement>
<region>District fédéral central</region>
</placeName>
</affiliation>
</author>
<author>
<name sortKey="Khlybov, E P" uniqKey="Khlybov E">E. P. Khlybov</name>
<affiliation wicri:level="1">
<inist:fA14 i1="03">
<s1>Laboratory of High Magnetic Fields and Low Temperatures</s1>
<s2>Wroclaw</s2>
<s3>POL</s3>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Pologne</country>
<wicri:noRegion>Laboratory of High Magnetic Fields and Low Temperatures</wicri:noRegion>
</affiliation>
<affiliation wicri:level="1">
<inist:fA14 i1="04">
<s1>L.F. Vereschagin Institute for Physics High Pressure</s1>
<s2>Troitsk</s2>
<s3>RUS</s3>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Russie</country>
<wicri:noRegion>L.F. Vereschagin Institute for Physics High Pressure</wicri:noRegion>
</affiliation>
</author>
</titleStmt>
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<date when="2001">2001</date>
<idno type="stanalyst">PASCAL 02-0073209 INIST</idno>
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<title level="j" type="main">Physica. C. Superconductivity and its applications</title>
</seriesStmt>
</fileDesc>
<profileDesc>
<textClass>
<keywords scheme="KwdEn" xml:lang="en">
<term>Annealing</term>
<term>Cerium oxides</term>
<term>Copper oxides</term>
<term>Crystal structure</term>
<term>Cuprates</term>
<term>Experimental study</term>
<term>High-Tc superconductors</term>
<term>Holmium oxides</term>
<term>Indium oxides</term>
<term>Lattice parameters</term>
<term>Multi-element compounds</term>
<term>Perovskites</term>
<term>Refinement</term>
<term>Stoichiometry</term>
<term>Strontium oxides</term>
<term>Superconductivity</term>
<term>XRD</term>
<term>Yttrium oxides</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Structure cristalline</term>
<term>Diffraction RX</term>
<term>Paramètre cristallin</term>
<term>Affinement</term>
<term>Recuit</term>
<term>Stoechiométrie</term>
<term>Supraconductivité</term>
<term>Supraconducteur haute température</term>
<term>Perovskites</term>
<term>Cuprate</term>
<term>Indium oxyde</term>
<term>Cuivre oxyde</term>
<term>Strontium oxyde</term>
<term>Yttrium oxyde</term>
<term>Holmium oxyde</term>
<term>Cérium oxyde</term>
<term>Composé n éléments</term>
<term>Etude expérimentale</term>
<term>(In,Cu)Sr2YCu2O6+δ</term>
<term>Cu In O Sr Y</term>
<term>(In,Cu)(Sr,Ho)2(Ho,Ce)2Cu2O8+δ</term>
<term>Ce Cu Ho In O Sr</term>
<term>6166F</term>
<term>7472J</term>
</keywords>
</textClass>
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<front>
<div type="abstract" xml:lang="en">The indium-based cuprates with perovskite-like structure (In, Cu)Sr
<sub>2</sub>
YCu
<sub>2</sub>
O
<sub>6+δ</sub>
and (In,Cu)(Sr,Ho)
<sub>2</sub>
(Ho,Ce)
<sub>2</sub>
Cu
<sub>2</sub>
O
<sub>8+δ</sub>
, belonging to the homologous series (In, Cu)(Sr,Ln)
<sub>2</sub>
(Ln, Sr)
<sub>k-1</sub>
Cu
<sub>k</sub>
O
<sub>2k+2+δ</sub>
with k = 1 (In,Cu-1212) and (In, Cu)(Sr, Ln)
<sub>2</sub>
(Ln, Ce)
<sub>k+1</sub>
Cu
<sub>2</sub>
O
<sub>2k+6+δ</sub>
with k = 1 (In,Cu-1222) have been obtained. Their structure has been refined at room temperature using X-ray powder diffraction data. The samples with the nominal compositions (In
<sub>0.5</sub>
Cu
<sub>0.5</sub>
)Sr
<sub>2</sub>
YCu
<sub>2</sub>
O
<sub>x</sub>
and (In
<sub>2/3</sub>
Cu
<sub>1/3</sub>
)(Ho
<sub>1/3</sub>
Ce
<sub>2/3</sub>
)
<sub>3</sub>
Sr
<sub>2</sub>
Cu
<sub>2</sub>
O
<sub>x</sub>
appeared to contain phases with lattice parameters a = 3.8163(1), c = 11.9785(6) A (In,Cu-1212, sp. gr. P4/mmm) and a = 3.8272(0), c = 29.0774(3) Å (In,Cu-1222, sp. gr. I4/mmm), respectively. Rietveld refinements were carried out. The real composition of these phases may be written as (In
<sub>0.89</sub>
Cu
<sub>0.11(3)</sub>
)Sr
<sub>2</sub>
YCu
<sub>2</sub>
O
<sub>6.98(4)</sub>
(In,Cu-1212) and (In
<sub>0.98</sub>
Cu
<sub>0.02(1)</sub>
)(Sr
<sub>1.25</sub>
Ho
<sub>0.75(2)</sub>
)(Ho
<sub>1.89</sub>
Ce
<sup>4-</sup>
<sub>0.11(5)</sub>
)Cu
<sub>2.00</sub>
O
<sub>9.00</sub>
(In,Cu-1222). The refined composition of these phases after oxygen treatment was formal to be (In
<sub>0.82</sub>
Cu
<sub>0.18(2)</sub>
)Sr
<sub>2</sub>
YCu
<sub>2</sub>
O
<sub>7.00</sub>
(In,Cu
<sup>*</sup>
-1212) and (In
<sub>0.87</sub>
Cu
<sub>0.13(1)</sub>
)(Sr
<sub>1.52</sub>
Ho
<sub>0.48(2)</sub>
)(Ho
<sub>1.95</sub>
Ce
<sup>4+</sup>
<sub>0.05(3)</sub>
)Cu
<sub>2</sub>
O
<sub>9.00</sub>
(In,Cu
<sup>*</sup>
-1222). The Cu formal charge (FC Cu) in the (In,Cu)-1212, calculated from electroneutrality condition of the refined phase composition, was almost the same as before (FC Cu ∼2.04) and after (FC Cu∼ 2.09) the oxygen treatment (underdoped phase). On the contrary, the FC Cu for the (In,Cu)-1222 increased after oxygen annealing (from -2.08 to -2.30) (overdoped phase). The non-optimal values of the Cu formal charge could be a possible reason for the absence of superconductivity in these samples.</div>
</front>
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<s2>3-4</s2>
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<fA08 i1="01" i2="1" l="ENG">
<s1>Crystal structure of In-based cuprates: (In, Cu)S[Sr]
<sub>2</sub>
YCu
<sub>2</sub>
O
<sub>6+δ</sub>
(1212), (In, Cu)(Sr, Ho)
<sub>2</sub>
(Ho, Ce
<sup>4+</sup>
)
<sub>2</sub>
Cu
<sub>2</sub>
O
<sub>8+δ</sub>
(1222)</s1>
</fA08>
<fA11 i1="01" i2="1">
<s1>AFANASSEVA (I. N.)</s1>
</fA11>
<fA11 i1="02" i2="1">
<s1>KUZ'MICHEVA (G. M.)</s1>
</fA11>
<fA11 i1="03" i2="1">
<s1>MITIN (A. V.)</s1>
</fA11>
<fA11 i1="04" i2="1">
<s1>KHLYBOV (E. P.)</s1>
</fA11>
<fA14 i1="01">
<s1>Department of Solid State Physics and Chemistry, M V. Lomonosov State Academy of Fine Chemical Technology, 86 Vernadsky prosp.</s1>
<s2>117571 Moscow</s2>
<s3>RUS</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</fA14>
<fA14 i1="02">
<s1>P.L. Kapitza Institute for Physics Problems</s1>
<s2>Moscow</s2>
<s3>RUS</s3>
<sZ>3 aut.</sZ>
</fA14>
<fA14 i1="03">
<s1>Laboratory of High Magnetic Fields and Low Temperatures</s1>
<s2>Wroclaw</s2>
<s3>POL</s3>
<sZ>4 aut.</sZ>
</fA14>
<fA14 i1="04">
<s1>L.F. Vereschagin Institute for Physics High Pressure</s1>
<s2>Troitsk</s2>
<s3>RUS</s3>
<sZ>4 aut.</sZ>
</fA14>
<fA20>
<s1>307-315</s1>
</fA20>
<fA21>
<s1>2001</s1>
</fA21>
<fA23 i1="01">
<s0>ENG</s0>
</fA23>
<fA43 i1="01">
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<s2>145C</s2>
<s5>354000103426250200</s5>
</fA43>
<fA44>
<s0>0000</s0>
<s1>© 2002 INIST-CNRS. All rights reserved.</s1>
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<s0>16 ref.</s0>
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<fA47 i1="01" i2="1">
<s0>02-0073209</s0>
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<fA60>
<s1>P</s1>
</fA60>
<fA61>
<s0>A</s0>
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<fA64 i1="01" i2="2">
<s0>Physica. C. Superconductivity and its applications</s0>
</fA64>
<fA66 i1="01">
<s0>NLD</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>The indium-based cuprates with perovskite-like structure (In, Cu)Sr
<sub>2</sub>
YCu
<sub>2</sub>
O
<sub>6+δ</sub>
and (In,Cu)(Sr,Ho)
<sub>2</sub>
(Ho,Ce)
<sub>2</sub>
Cu
<sub>2</sub>
O
<sub>8+δ</sub>
, belonging to the homologous series (In, Cu)(Sr,Ln)
<sub>2</sub>
(Ln, Sr)
<sub>k-1</sub>
Cu
<sub>k</sub>
O
<sub>2k+2+δ</sub>
with k = 1 (In,Cu-1212) and (In, Cu)(Sr, Ln)
<sub>2</sub>
(Ln, Ce)
<sub>k+1</sub>
Cu
<sub>2</sub>
O
<sub>2k+6+δ</sub>
with k = 1 (In,Cu-1222) have been obtained. Their structure has been refined at room temperature using X-ray powder diffraction data. The samples with the nominal compositions (In
<sub>0.5</sub>
Cu
<sub>0.5</sub>
)Sr
<sub>2</sub>
YCu
<sub>2</sub>
O
<sub>x</sub>
and (In
<sub>2/3</sub>
Cu
<sub>1/3</sub>
)(Ho
<sub>1/3</sub>
Ce
<sub>2/3</sub>
)
<sub>3</sub>
Sr
<sub>2</sub>
Cu
<sub>2</sub>
O
<sub>x</sub>
appeared to contain phases with lattice parameters a = 3.8163(1), c = 11.9785(6) A (In,Cu-1212, sp. gr. P4/mmm) and a = 3.8272(0), c = 29.0774(3) Å (In,Cu-1222, sp. gr. I4/mmm), respectively. Rietveld refinements were carried out. The real composition of these phases may be written as (In
<sub>0.89</sub>
Cu
<sub>0.11(3)</sub>
)Sr
<sub>2</sub>
YCu
<sub>2</sub>
O
<sub>6.98(4)</sub>
(In,Cu-1212) and (In
<sub>0.98</sub>
Cu
<sub>0.02(1)</sub>
)(Sr
<sub>1.25</sub>
Ho
<sub>0.75(2)</sub>
)(Ho
<sub>1.89</sub>
Ce
<sup>4-</sup>
<sub>0.11(5)</sub>
)Cu
<sub>2.00</sub>
O
<sub>9.00</sub>
(In,Cu-1222). The refined composition of these phases after oxygen treatment was formal to be (In
<sub>0.82</sub>
Cu
<sub>0.18(2)</sub>
)Sr
<sub>2</sub>
YCu
<sub>2</sub>
O
<sub>7.00</sub>
(In,Cu
<sup>*</sup>
-1212) and (In
<sub>0.87</sub>
Cu
<sub>0.13(1)</sub>
)(Sr
<sub>1.52</sub>
Ho
<sub>0.48(2)</sub>
)(Ho
<sub>1.95</sub>
Ce
<sup>4+</sup>
<sub>0.05(3)</sub>
)Cu
<sub>2</sub>
O
<sub>9.00</sub>
(In,Cu
<sup>*</sup>
-1222). The Cu formal charge (FC Cu) in the (In,Cu)-1212, calculated from electroneutrality condition of the refined phase composition, was almost the same as before (FC Cu ∼2.04) and after (FC Cu∼ 2.09) the oxygen treatment (underdoped phase). On the contrary, the FC Cu for the (In,Cu)-1222 increased after oxygen annealing (from -2.08 to -2.30) (overdoped phase). The non-optimal values of the Cu formal charge could be a possible reason for the absence of superconductivity in these samples.</s0>
</fC01>
<fC02 i1="01" i2="3">
<s0>001B60A66F1</s0>
</fC02>
<fC02 i1="02" i2="3">
<s0>001B70D72J</s0>
</fC02>
<fC03 i1="01" i2="3" l="FRE">
<s0>Structure cristalline</s0>
<s5>02</s5>
</fC03>
<fC03 i1="01" i2="3" l="ENG">
<s0>Crystal structure</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="3" l="FRE">
<s0>Diffraction RX</s0>
<s5>03</s5>
</fC03>
<fC03 i1="02" i2="3" l="ENG">
<s0>XRD</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="3" l="FRE">
<s0>Paramètre cristallin</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="3" l="ENG">
<s0>Lattice parameters</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE">
<s0>Affinement</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG">
<s0>Refinement</s0>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA">
<s0>Afinamiento</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE">
<s0>Recuit</s0>
<s5>07</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG">
<s0>Annealing</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="3" l="FRE">
<s0>Stoechiométrie</s0>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="3" l="ENG">
<s0>Stoichiometry</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="3" l="FRE">
<s0>Supraconductivité</s0>
<s5>09</s5>
</fC03>
<fC03 i1="07" i2="3" l="ENG">
<s0>Superconductivity</s0>
<s5>09</s5>
</fC03>
<fC03 i1="08" i2="3" l="FRE">
<s0>Supraconducteur haute température</s0>
<s5>10</s5>
</fC03>
<fC03 i1="08" i2="3" l="ENG">
<s0>High-Tc superconductors</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="3" l="FRE">
<s0>Perovskites</s0>
<s5>11</s5>
</fC03>
<fC03 i1="09" i2="3" l="ENG">
<s0>Perovskites</s0>
<s5>11</s5>
</fC03>
<fC03 i1="10" i2="3" l="FRE">
<s0>Cuprate</s0>
<s2>NA</s2>
<s5>12</s5>
</fC03>
<fC03 i1="10" i2="3" l="ENG">
<s0>Cuprates</s0>
<s2>NA</s2>
<s5>12</s5>
</fC03>
<fC03 i1="11" i2="3" l="FRE">
<s0>Indium oxyde</s0>
<s2>NK</s2>
<s5>13</s5>
</fC03>
<fC03 i1="11" i2="3" l="ENG">
<s0>Indium oxides</s0>
<s2>NK</s2>
<s5>13</s5>
</fC03>
<fC03 i1="12" i2="3" l="FRE">
<s0>Cuivre oxyde</s0>
<s2>NK</s2>
<s5>14</s5>
</fC03>
<fC03 i1="12" i2="3" l="ENG">
<s0>Copper oxides</s0>
<s2>NK</s2>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="3" l="FRE">
<s0>Strontium oxyde</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="13" i2="3" l="ENG">
<s0>Strontium oxides</s0>
<s2>NK</s2>
<s5>15</s5>
</fC03>
<fC03 i1="14" i2="3" l="FRE">
<s0>Yttrium oxyde</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="14" i2="3" l="ENG">
<s0>Yttrium oxides</s0>
<s2>NK</s2>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="3" l="FRE">
<s0>Holmium oxyde</s0>
<s2>NK</s2>
<s5>17</s5>
</fC03>
<fC03 i1="15" i2="3" l="ENG">
<s0>Holmium oxides</s0>
<s2>NK</s2>
<s5>17</s5>
</fC03>
<fC03 i1="16" i2="3" l="FRE">
<s0>Cérium oxyde</s0>
<s2>NK</s2>
<s5>18</s5>
</fC03>
<fC03 i1="16" i2="3" l="ENG">
<s0>Cerium oxides</s0>
<s2>NK</s2>
<s5>18</s5>
</fC03>
<fC03 i1="17" i2="3" l="FRE">
<s0>Composé n éléments</s0>
<s5>19</s5>
</fC03>
<fC03 i1="17" i2="3" l="ENG">
<s0>Multi-element compounds</s0>
<s5>19</s5>
</fC03>
<fC03 i1="18" i2="3" l="FRE">
<s0>Etude expérimentale</s0>
<s5>20</s5>
</fC03>
<fC03 i1="18" i2="3" l="ENG">
<s0>Experimental study</s0>
<s5>20</s5>
</fC03>
<fC03 i1="19" i2="3" l="FRE">
<s0>(In,Cu)Sr2YCu2O6+δ</s0>
<s4>INC</s4>
<s5>52</s5>
</fC03>
<fC03 i1="20" i2="3" l="FRE">
<s0>Cu In O Sr Y</s0>
<s4>INC</s4>
<s5>53</s5>
</fC03>
<fC03 i1="21" i2="3" l="FRE">
<s0>(In,Cu)(Sr,Ho)2(Ho,Ce)2Cu2O8+δ</s0>
<s4>INC</s4>
<s5>54</s5>
</fC03>
<fC03 i1="22" i2="3" l="FRE">
<s0>Ce Cu Ho In O Sr</s0>
<s4>INC</s4>
<s5>55</s5>
</fC03>
<fC03 i1="23" i2="3" l="FRE">
<s0>6166F</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="24" i2="3" l="FRE">
<s0>7472J</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC07 i1="01" i2="3" l="FRE">
<s0>Composé minéral</s0>
<s5>48</s5>
</fC07>
<fC07 i1="01" i2="3" l="ENG">
<s0>Inorganic compounds</s0>
<s5>48</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE">
<s0>Métal transition composé</s0>
<s5>49</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG">
<s0>Transition element compounds</s0>
<s5>49</s5>
</fC07>
<fC07 i1="03" i2="3" l="FRE">
<s0>Lanthanide composé</s0>
<s5>50</s5>
</fC07>
<fC07 i1="03" i2="3" l="ENG">
<s0>Rare earth compounds</s0>
<s5>50</s5>
</fC07>
<fN21>
<s1>037</s1>
</fN21>
</pA>
</standard>
</inist>
</record>

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   |wiki=   *** parameter Area/wikiCode missing *** 
   |area=    IndiumV3
   |flux=    Russie
   |étape=   Analysis
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   |clé=     Pascal:02-0073209
   |texte=   Crystal structure of In-based cuprates: (In, Cu)S[Sr]2YCu2O6+δ (1212), (In, Cu)(Sr, Ho)2(Ho, Ce4+)2Cu2O8+δ(1222)
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